The Synthesis and Cyclic Voltammetry of Select Ferrocene Piano-Stool Isocyanide Complexes
Document Type
Article
Publication Date
3-15-2011
Abstract
Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.
DOI
10.1016/j.ica.2011.01.025
Montclair State University Digital Commons Citation
Humphrey, Brian; Castilo, Raidiri E.; Vega, Amy H.; Feliciano, Argelia; and Squires, Marjorie E., "The Synthesis and Cyclic Voltammetry of Select Ferrocene Piano-Stool Isocyanide Complexes" (2011). Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works. 125.
https://digitalcommons.montclair.edu/chem-biochem-facpubs/125