Title

2-Azabicyclo[2.2.1]Hept-5-Enes from 7-Azabicyclo[2.2.1]Heptadienes by Tandem Intermolecular Radical Addition - Homoallylic Radical Rearrangement

Document Type

Article

Publication Date

5-21-2001

Abstract

Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.

DOI

10.1039/b101984h

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