Photoisomerizable Heterodienes Derived from a Phosphine Borane

Authors

Magnus Bebbington, Montclair State UniversityFollow
Sébastien Bontemps, Université de ToulouseFollow
Ghenwa Bouhadir, Université Paul SabatierFollow
Didier Bourissou, Université Paul SabatierFollow

Document Type

Article

Publication Date

7-2-2007

Journal / Book Title

Angewandte Chemie International Edition

Abstract

(Chemical Equation Presented) Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R = iPr, R′ = mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N α→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.

DOI

10.1002/anie.200605078

Montclair State University Digital Commons Citation

Bebbington, Magnus; Bontemps, Sébastien; Bouhadir, Ghenwa; and Bourissou, Didier, "Photoisomerizable Heterodienes Derived from a Phosphine Borane" (2007). Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works. 15.
https://digitalcommons.montclair.edu/chem-biochem-facpubs/15