Ion-Molecule Reactions for the Differentiation of Primary, Secondary and Tertiary Hydroxyl Functionalities in Protonated Analytes in a Tandem Mass Spectrometer

Authors

Mingkun Fu, Purdue University
Penggao Duan, Purdue University
Jinshan Gao, Montclair State UniversityFollow
Hilkka I. Kenttämaa, Purdue University

Document Type

Article

Publication Date

12-21-2012

Journal / Book Title

Analyst

Abstract

A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.

DOI

10.1039/c2an35986c

Montclair State University Digital Commons Citation

Fu, Mingkun; Duan, Penggao; Gao, Jinshan; and Kenttämaa, Hilkka I., "Ion-Molecule Reactions for the Differentiation of Primary, Secondary and Tertiary Hydroxyl Functionalities in Protonated Analytes in a Tandem Mass Spectrometer" (2012). Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works. 29.
https://digitalcommons.montclair.edu/chem-biochem-facpubs/29