A 1,1′-Ferrocenyl Phosphine-Borane: Synthesis, Structure and Evaluation in Rh-Catalyzed Hydroformylation
Document Type
Article
Publication Date
8-1-2010
Abstract
The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.
DOI
10.1039/c0nj00117a
Montclair State University Digital Commons Citation
Bebbington, Magnus; Bontemps, Sébastien; Bouhadir, Ghenwa; Hanton, Martin J.; Tooze, Robert P.; Van Rensburg, Hendrick; and Bourissou, Didier, "A 1,1′-Ferrocenyl Phosphine-Borane: Synthesis, Structure and Evaluation in Rh-Catalyzed Hydroformylation" (2010). Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works. 363.
https://digitalcommons.montclair.edu/chem-biochem-facpubs/363