Title

A 1,1′-Ferrocenyl Phosphine-Borane: Synthesis, Structure and Evaluation in Rh-Catalyzed Hydroformylation

Document Type

Article

Publication Date

8-1-2010

Abstract

The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

DOI

10.1039/c0nj00117a

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