2-Azabicyclo[2.2.1]Hept-5-Enes from 7-Azabicyclo[2.2.1]Heptadienes by Tandem Intermolecular Radical Addition - Homoallylic Radical Rearrangement

Authors

David M. Hodgson, University of Oxford
Magnus Bebbington, Montclair State UniversityFollow
Paul Willis, University of OxfordFollow

Document Type

Article

Publication Date

5-21-2001

Abstract

Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.

DOI

10.1039/b101984h

Montclair State University Digital Commons Citation

Hodgson, David M.; Bebbington, Magnus; and Willis, Paul, "2-Azabicyclo[2.2.1]Hept-5-Enes from 7-Azabicyclo[2.2.1]Heptadienes by Tandem Intermolecular Radical Addition - Homoallylic Radical Rearrangement" (2001). Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works. 67.
https://digitalcommons.montclair.edu/chem-biochem-facpubs/67